基于混合近似法的纤维梁单元非线性求解方法#br#

环境荷载作用下土木工程结构往往产生较大的非线性变形,包括材料非线性和几何大变形两部分,而两者非线性问题的数值求解往往需要花费高昂的计算代价。隔离非线性有限元法是将材料应变分解为弹性与塑性两部分,在控制方程中实现刚度矩阵的弹塑性分离,使用Woodbury公式进行非线性求解。目前,该方法仅用于求解局部材料非线性问题。文章基于隔离非线性有限元法,推导同时考虑材料和几何非线性（简称混合非线性）的纤维梁单元控制方程;依据Woodbury公式和组合近似法的基本理论,提出混合近似法的高效非线性求解方法,并利用时间复杂度理论,对该方法与传统有限元法进行计算效率对比分析;将提出的方法应用于某钢框架结构的地震非线性反应分析,计算结果表明：文中方法可以在求解材料非线性时考虑几何大变形问题,在保证计算精度的同时使计算效率得到明显提升。     

过期药呋塞米在醋酸溶液中对冷轧钢的缓蚀作用

通过电导率测量、pH测量、同步热分析(STA)、Tafel极化曲线法和电化学交流阻抗谱法研究了不同浓度和温度下过期药呋塞米在1 mol/L的醋酸溶液中对冷轧钢缓蚀作用。实验结果表明:过期药呋塞米在1 mol/L的醋酸溶液中对冷轧钢有较好的缓蚀效果,且缓蚀率随着缓蚀剂浓度和温度的增加而增大。该缓蚀剂在醋酸中对钢是一种抑制阴极和阳极的混合型缓蚀剂。缓蚀剂在冷轧钢表面的吸附符合Langmuir吸附等温式,其吸附是自发、物理吸附过程。同步热分析还说明了该缓蚀剂易稳定吸附在冷轧钢表面。     

用主成分回归法同时测定Zn~(2+)、Cd~(2+)、Pb~(2+)和Cu~(2+)的研究

使用聚类分析对不同缓冲体系下Zn2+、Cd2+、Pb2+、Cu2+的吸光度光谱数据分析,通过数量化的方法确定pH值=6.0的最佳缓冲体系。通过单因素实验分析确定缓冲溶液用量为5.0ml、显色剂用量为3.0ml、环糊精用量为2.0ml及最佳显色时间10min。绘制Zn2+、Cd2+、Pb2+、Cu2+的标准曲线,结果表明其具有良好的线性范围和线性加和性。应用主成分回归法计算含有干扰离子的待测水样中Zn2+、Cd2+、Pb2+、Cu2+的浓度,并计算出平均回收率为109.64%、92.77%、98.18%、102.28%,相对标准偏差为11.48%、11.12%、6.34%、4.72%。     

Recent progress in thermal analysis of polymers: experimental techniques and a new aspect of temperature in measurement of material properties

Thermal analysis has been utilized in polymer research for a long time and its usefulness is widely recognized. High‐performance commercial instruments have driven significant progress in the thermal studies of polymers. On the other hand, new experimental instruments have been developed in laboratories as well. In this paper attention is paid to the latter category. The laboratory‐made instrument focused on the target material and/or phenomena provides data that are not available from other techniques. Experiments using the temperature modulation technique, which has been successfully utilized in laboratory‐made instruments, are introduced in this paper. The temperature modulation technique reveals a new aspect of temperature useful for studies of material properties. © 2016 Society of Chemical Industry     

地面出入式盾构法隧道施工技术研究综述

地面出入式盾构(GPST)由日本株式会社大林组研发,作为一种新型盾构隧道施工方法,无需传统盾构的端头工作井,明显减小对周围环境的影响,同时缩短工期。该技术目前的实践工程较少,存在多方面工程技术难题。根据已有研究资料,阐述地面出入式盾构的相关技术难题,主要从隧道衬砌、盾构姿态、同步注浆等几个方面进行总结,分析现有研究不足之处,提出需要进一步研究的方向和研究思路。     

A numerical scheme based on compact integrated-RBFs and Adams–Bashforth/Crank–Nicolson algorithms for diffusion and unsteady fluid flow problems

This paper presents a high-order approximation scheme based on compact integrated radial basis function (CIRBF) stencils and second-order Adams–Bashforth/Crank–Nicolson algorithms for solving time-dependent problems in one and two space dimensions. We employ CIRBF stencils, where the RBF approximations are locally constructed through integration and expressed in terms of nodal values of the function and its derivatives, to discretise the spatial derivatives in the governing equation. We adopt the Adams–Bashforth and Crank–Nicolson algorithms, which are second-order accurate, to discretise the temporal derivatives. The performance of the proposed scheme is investigated numerically through the solution of several test problems, including heat transfer governed by the diffusion equation, shock wave propagation and shock-like solution governed by the Burgers' equation, and torsionally oscillating lid-driven cavity flow governed by the Navier–Stokes equation in the primitive variables. Numerical experiments show that the proposed scheme is stable and high-order accurate in reference to the exact solution of analytic test problems and achieves a good agreement with published results for other test problems.     

基于GIS和SLAM的机器人大范围环境自主导航

机器人自主导航技术的基础是其自定位能力,同时同步定位与建图(SLAM)是实现机器人自定位的重要方法。目前由于大规模SLAM技术发展的限制,机器人很难实现在大范围环境下进行建图和导航,并且尚没有结合SLAM和实际地理空间信息指导大范围机器人导航的完整自主导航系统。提出基于GIS和SLAM的机器人大范围环境自主导航方法,利用真实的城市空间路网信息,以地理信息系统(GIS)空间数据库的存储和计算能力为数据支撑,基于提出的大范围导航算法,实现了一套包含空间数据库、SLAM、导航算法的完整系统,具有良好的可复用性和可扩展性,符合实际生活场景,可以指导机器人进行大范围条件下的导航和建图行为。同时通过对机器人激光建图信息的存储,使得再次经过本区域的机器人可以在户外精确定位,实现在室外GPS缺失或误差条件下自身位置的修正。此外地图信息的存储可以实现多机器人对地图信息的复用,为多机器人的规划提供支撑。同时将人类世界的空间信息与机器人建图信息相结合,细化和丰富了原有的空间信息。     

化学计量学-荧光分析法同时测定甲酚的3种同分异构体

利用化学计量学中的主成分回归法(PCR)和荧光分析法相结合,并用遗传算法(GA)对其进行优化,建立了同时测定甲酚混合物中3种同分异构体的新方法。在p H 4.92的磷酸氢二钠-磷酸二氢钾缓冲介质中,邻、间、对甲酚浓度在3.00~12.0μg/m L范围内,以λ=274 nm为定激发波长,测定300~335 nm波长范围内的荧光光谱,分别使用PCR和GA-PCR两种校正模型对光谱数据进行解析,并同时对3种异构体进行定量分析。研究结果表明,两种方法对邻、间、对甲酚进行预测的平均回收率分别为89.0%、107.5%、100.4%和100.6%、99.1%、98.0%,均方根预测误差分别为0.71、0.49、0.15μg/m L和0.17、0.16、0.21μg/m L,精密度试验的相对标准偏差均小于1.0%,且经GA优化后的PCR方法的加标回收率得到了明显改善,均方根预测误差减小50%,具有更好的准确度。     

SBP-SAT方法及其在波动领域的应用

基于分部求和(Summation By Parts)方法和同时逼近项(Simultaneous Approximation Terms)技术建立的有限差分方法,具有更高的精度和稳定性。同时在介质几何不连续、参数突变条件具有较大的优势。国内对SBP-SAT方法的相关研究目前较少,论文对该方法的研究背景,方法发展过程进行了介绍并基于SBP-SAT方法和弹性波动理论,结合初边值条件,推导出曲线网格条件下的弹性波动SBP-SAT离散方程。最后,通过数值模拟实现地震波传播过程,介绍该方法在地震数值模拟领域中的应用价值和前景。     

Simple validated method for simultaneous determination of deoxynivalenol,nivalenol, and their 3-β-D-glucosides in baby formula and Korean rice wine via HPLC-UV with immunoaffinity cleanup

A simple and reliable method for the simultaneous determination of major type B trichothecene mycotoxins, deoxynivalenol (DON) and nivalenol (NIV), along with their 3-β-d-glucosides (DON-3-glucoside (DON3G) and NIV-3-glucoside (NIV3G)) in baby formula and Korean rice wine was validated in the present study. The method was based on immunoaffinity cleanup followed by analysis using an HPLC-UV technique. The method was validated in-house for two matrices as follows: linearity (R² > 0.99) was established in the range of 20–1000 μg kg^–1; accuracy (expressed as recovery) ranged from 78.7 to 106.5% for all the analytes; good intermediate precision (relative standard deviation < 12%), and adequate detection and quantitation limits (< 4.4 and < 13.3 μg kg^–1, respectively) were achieved. Furthermore, the estimated measurement expanded uncertainty was determined to be 4–24%. The validated method was successfully applied to the analysis of 31 baby formulas and Korean rice wines marketed in Korea.